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    7012-16-0

    Catalog No. EBD22044

    CAS 7012-16-0

    Name 2,7-Dichloro-9H-fluorene

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    Basic Information

    Synonyms: 2,7-Dichlorofluorene 2,7-dichloro-9H-fluorene

    Molecular Formula: C13H8Cl2

    Molecular Weight: 235.11

    MDL Number: MFCD00032840

    Categories: Materials Chemistry > Optoelectronic and Organic Semiconductor Materials > Thiophene, Pyrene, and Fluorene Derivatives Synthetic Chemistry > Organic Building Blocks > Other Organic Building Blocks

    Product Description:
    2,7-Dichlorofluorene is an organic compound featuring a fluorene core substituted with chlorine atoms at the 2 and 7 positions. This specific substitution pattern is crucial for its electronic properties, making it a versatile and important building block in materials science. Its primary and most significant application is as a key monomer or precursor in the synthesis of conjugated polymers and small molecules for organic electronic devices. The chlorine atoms serve as excellent leaving groups in cross-coupling reactions (e.g., Suzuki, Stille), enabling the efficient construction of extended π-conjugated systems. It is extensively used to create polyfluorenes and their copolymers, which are fundamental materials for organic light-emitting diodes (OLEDs), organic photovoltaics (OPVs), and organic field-effect transistors (OFETs). The fluorene unit contributes to high charge carrier mobility and good thermal stability. Beyond its role in advanced materials, 2,7-dichlorofluorene is also a valuable synthetic intermediate in organic chemistry for constructing complex polycyclic aromatic frameworks. It is handled as a solid and requires standard precautions for handling halogenated aromatic compounds.
    Physical Properties

    Melting Point: 126-128

    Boiling Point: 370.7 °C at 760 mmHg

    Flash Point: 185.3 °C

    Density: 1.365 g/cm3

    Analytical Data

    Appearance: Off-white solid

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