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    55135-66-5

    Catalog No. EBD46870

    CAS 55135-66-5

    Name 9-Bromo-9-phenyl-9H-fluorene

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    Basic Information

    Synonyms: 9-bromo-9-phenylfluorene 9-Bromo-9-phenylfuorene 9-Bromo-9-phenyl-9H-fluorene 1-bromo-9-phenyl-9H-fluorene

    Molecular Formula: C19H13Br

    Molecular Weight: 321.21

    MDL Number: MFCD00075522

    Categories: Materials Chemistry > Optoelectronic and Organic Semiconductor Materials > OLED and Organic Optoelectronic Precursors Synthetic Chemistry > Organic Building Blocks > Halogenated Compounds

    Product Description:
    9-Bromo-9-phenylfluorene is an organic compound featuring a fluorene core substituted with a bromine atom and a phenyl group at the 9-position. This structure makes it a versatile building block, particularly valued for its ability to introduce the 9-phenylfluorenyl group, which can act as a bulky, rigid, and aromatic substituent. Its primary and most significant application is in the field of materials science, specifically in the synthesis of advanced organic electronic materials. It serves as a crucial precursor or intermediate for the development of organic light-emitting diodes (OLEDs), organic field-effect transistors (OFETs), and other optoelectronic devices. The molecule is used to construct host materials, hole-transporting materials (HTMs), and emissive layer components, where the 9-phenylfluorene moiety contributes to thermal stability, morphological stability, and favorable electronic properties. As a brominated aromatic compound, it is also a common and useful synthetic intermediate in organic chemistry, participating in various cross-coupling reactions (e.g., Suzuki, Stille, Negishi couplings) to form more complex conjugated systems. Therefore, it finds use both as a specialized material precursor and a general organic synthesis building block.
    Physical Properties

    Melting Point: 99-101 °C(lit.)

    Boiling Point: 394.324 °C at 760 mmHg

    Flash Point: 172.533 °C

    Density: 1.426 g/cm3

    Solubility: Insoluble in water

    mg g kg ml l t