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    544461-38-3

    Catalog No. EBD3063798

    CAS 544461-38-3

    Name (S,S)-F-BINAPHANE

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    Basic Information

    Synonyms: (S,S)-F-BINAPHANE 1,1WEI-BIS[(S)-4,5-DIHYDRO-3H-BINAPHTHO[2,1-C:1WEI,2WEI-E]PHOSPHEPINO]FERROCENE,1,1WEI-BIS[(11BS)-3,5-DIHYDRO-4H-DINAPHTHO[2,1-C:1WEI,2WEI-E]PHOSPHENPIN-4YL]FERROCENE Ferrocene,1,1'-bis[(11bS)-3,5-dihydro-4H-dinaphtho[2,1-c:1',2'-e]phosphepin-4-yl]- 1,1μ-Bis[(S)-4,5-dihydro-3H-binaphtho[2,1-c:1μ,2μ-e]phosphepino]ferrocene,1,1μ-Bis[(11bs)-3,5-dihydro-4H-dinaphtho[2,1-c:1μ,2μ-e]phosphenpin-4yl]ferrocene

    Molecular Formula: C54H32FeP2

    Molecular Weight: 798.64

    Categories: Synthetic Chemistry > Catalysts and Ligands > Chiral Ligands Synthetic Chemistry > Catalysts and Ligands > Phosphorus Ligands

    Product Description:
    (S,S)-F-BINAPHANE is a chiral, ferrocene-based bisphosphine ligand. Its structure features a ferrocene core symmetrically substituted with two (S)-4,5-dihydro-3H-dinaphtho[2,1-c:1',2'-e]phosphole units, which are electron-rich and sterically demanding. This configuration endows the ligand with a well-defined, rigid chiral environment. This ligand is primarily employed in asymmetric catalysis, particularly in transition-metal-catalyzed reactions. It has demonstrated high efficiency and enantioselectivity in hydrogenation reactions, such as the asymmetric hydrogenation of functionalized olefins, ketones, and imines. The ferrocenyl backbone and the binaphthyl-derived phosphole moieties contribute to its stability and unique stereocontrol properties, making it a valuable tool for the synthesis of chiral pharmaceutical intermediates and fine chemicals. As a specialized chiral ligand, (S,S)-F-BINAPHANE is not a commodity chemical but a high-value research and development reagent used in academic and industrial laboratories focused on asymmetric synthesis. Its handling requires standard precautions for air- and moisture-sensitive organometallic compounds.
    Physical Properties
    mg g kg ml l t