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    24400-84-8

    Catalog No. EBD20065

    CAS 24400-84-8

    Name Allyltriisopropylsilane

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    Basic Information

    Synonyms: Ethyl3-(4-methoxyphenyl)acrylate Allyltriisopropylsilane

    Molecular Formula: C12H26Si

    Molecular Weight: 198.42

    MDL Number: MFCD00075115

    Categories: Materials Chemistry > Polymers and Macromolecular Materials > Functional Copolymer Monomers Synthetic Chemistry > Organic Building Blocks > Other Organic Building Blocks

    Product Description:
    Allyltriisopropylsilane is an organosilicon compound characterized by an allyl group attached to a triisopropylsilyl protecting group. It is a colorless to pale yellow liquid with the molecular formula C12H26Si. Its primary application is as a versatile monomer in polymer chemistry, particularly in the synthesis of functional polymers and copolymers. The allyl group readily undergoes free-radical polymerization and other addition reactions, while the bulky triisopropylsilyl group can impart specific properties like hydrophobicity or serve as a handle for further chemical modification. This makes it valuable for creating materials with tailored surface characteristics, in coatings, and as a precursor for silicon-containing polymers. In synthetic organic chemistry, it is also employed as a reagent, notably in the Hosomi-Sakurai reaction, where it acts as an allylating agent for electrophiles like carbonyl compounds in the presence of a Lewis acid catalyst. The silyl group enhances the nucleophilicity of the allyl moiety and can influence the regioselectivity of the reaction.
    Physical Properties

    Melting Point: < 0 °C

    Boiling Point: 210.7 °C at 760 mmHg

    Flash Point: 76 °C

    Density: 0.824 g/mL at 25 °C(lit.)

    Refractivity: n20/D 1.467(lit.)

    Analytical Data

    Appearance: colorless transparent liquid

    mg g kg ml l t