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    13428-80-3

    Catalog No. EBD267696

    CAS 13428-80-3

    Name Hf(OEt)4

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    Basic Information

    Synonyms: Hf(OEt)4 hafnium(IV)ethoxide tetraethoxyhafnium hafniumethoxide hafniumtetraethanolate hafniumtetramethoxide hafniumtetraethoxide hafnium(iv)ethoxide99% hafniumethoxide,99.9%(metalsbasis) hafnium(iv)ethoxide,99%

    Molecular Formula: C8H20HfO4

    Molecular Weight: 358.73

    MDL Number: MFCD00070459

    Categories: Materials Chemistry > Inorganic and Functional Nanomaterials > Metal Oxide Precursors Synthetic Chemistry > Organometallic Reagents > Other Organometallic Reagents

    Product Description:
    Hafnium(IV) ethoxide, with the CAS number 13428-80-3, is a metal alkoxide compound. It is a moisture-sensitive solid or liquid, typically handled under inert atmospheres. Its chemical formula is often represented as Hf(OCH₂CH₃)₄, indicating a hafnium center coordinated by four ethoxide ligands. The primary and most significant application of hafnium ethoxide is as a precursor in materials science, particularly in the synthesis of hafnium oxide (HfO₂) thin films via chemical vapor deposition (CVD) or atomic layer deposition (ALD). Hafnium oxide is a critical high-κ dielectric material used in advanced semiconductor devices and gate insulators in microprocessors. It is also employed in the sol-gel synthesis of other hafnium-based ceramics and nanomaterials. From a synthetic chemistry perspective, hafnium ethoxide falls under the category of organometallic reagents. It can act as a Lewis acid catalyst or a reagent in organic transformations and polymerization reactions, such as the ring-opening polymerization of cyclic esters. However, its use is highly specialized compared to more common organometallics like Grignard or organolithium reagents.
    Physical Properties

    Melting Point: 178-180°C

    Boiling Point: 180-200°C 13mm

    Flash Point: 8.9°C

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