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    119-91-5

    Catalog No. EBD35018

    CAS 119-91-5

    Name 2,2'-biquinoline

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    Basic Information

    Synonyms: cuproin cuproine 2,2'-diquinolyl 2,2-biquinoline 2,2'-biquinolyl alpha,alpha'-diquinolyl 2,2'-quinolyl 2,2-Diquinolyl Cuproin~2,2-Diquinolyl 2,2-DIQUINOLEINE 2,3'-biquinoline 2,2'-Biquinoline 2,2-Biquinolyl [2,2']biquinolinyl

    Molecular Formula: C18H12N2

    Molecular Weight: 256.3

    MDL Number: MFCD00006740

    Categories: Materials Chemistry > Optoelectronic and Organic Semiconductor Materials > OLED and Organic Optoelectronic Precursors

    Product Description:
    2,2'-Biquinoline is an organic compound consisting of two quinoline units linked at the 2-position. It is a pale yellow to yellow crystalline solid with a molecular formula of C18H12N2. This compound is a classic chelating ligand, particularly known for forming intensely colored complexes with various metal ions, most notably the orange-red complex with cuprous ion (Cu(I)), which has been historically used in analytical chemistry for the colorimetric determination of copper. The primary and significant application of 2,2'-biquinoline is in the field of materials science, specifically in the development of organic light-emitting diodes (OLEDs) and other organic electronic devices. It serves as a crucial building block or precursor for synthesizing more complex organic semiconductors, electron-transporting materials (ETMs), and host materials due to its rigid, planar, and conjugated structure which facilitates charge transport. Its derivatives are explored for use in the emissive or charge-transport layers of OLEDs. From a synthetic chemistry perspective, 2,2'-biquinoline is also a valuable heterocyclic building block. Its structure provides a platform for further functionalization, making it useful in the preparation of more elaborate ligands for catalysis or advanced organic materials. It is commercially available and handled as a standard laboratory chemical for research purposes.
    Physical Properties

    Melting Point: 192-195 °C(lit.)

    Boiling Point: 456.1 °C at 760 mmHg

    Flash Point: 203.6 °C

    Density: 1.223 g/cm3

    Analytical Data

    Appearance: slightly yellow to light beige shiny flakes

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