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    1160861-60-8

    Catalog No. EBD2013975

    CAS 1160861-60-8

    Name jackiePhos

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    Basic Information

    Synonyms: 2-Di[3,5-bis(trifluoromethyl)phenylphosphino]-3,6-dimethoxy-2'-4'-6'-tri-i-propyl-1,1'-biphenyl JackiePhos bis(3,5-bis(trifluoromethyl)phenyl)(2',4',6'-triisopropyl-3,6-dimethoxybiphenyl-2-yl)phosphine

    Molecular Formula: C39H37F12O2P

    Molecular Weight: 796.66

    Categories: Materials Chemistry > Optoelectronic and Organic Semiconductor Materials > OLED and Organic Optoelectronic Precursors Synthetic Chemistry > Catalysts and Ligands > Phosphorus Ligands

    Product Description:
    This compound, 2-{Bis[3,5-bis(trifluoromethyl)phenyl]phosphino}-3,6-dimethoxy-2',4',6'-triisopropyl-1,1'-biphenyl, is a specialized phosphine ligand. It is structurally characterized by a biphenyl backbone substituted with methoxy and bulky isopropyl groups, and a phosphorus center bearing two electron-withdrawing 3,5-bis(trifluoromethyl)phenyl substituents. Its primary application is in the field of organic electronics and materials science. It serves as a crucial precursor or ligand in the synthesis of organometallic complexes used as emitters or hosts in Organic Light-Emitting Diodes (OLEDs). The sterically demanding and electron-deficient design of this ligand is key to tuning the electronic properties, stability, and performance of the resulting metal complexes (e.g., iridium or platinum complexes) for high-efficiency phosphorescent OLED devices. As a highly functionalized, air-sensitive phosphine, it falls under the category of advanced ligands in synthetic chemistry. Its specific structural motifs are engineered to facilitate challenging cross-coupling reactions or to create complexes with specific luminescent properties, making it a valuable tool in both materials synthesis and catalysis research.
    Physical Properties

    Melting Point: 186-190 °C

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